| 1 | Erling HaalandPenalty goals: 3 | Manchester City | 27 |
| 2 | Igor ThiagoPenalty goals: 8 | Brentford | 22 |
| 3 | Antoine SemenyoPenalty goals: 1 | Manchester City | 17 |
| 4 | Ollie WatkinsPenalty goals: 0 | Aston Villa | 16 |
| 5 | João PedroPenalty goals: 0 | Chelsea | 15 |
| 6 | Morgan Gibbs-WhitePenalty goals: 1 | Nottingham Forest | 15 |
| 7 | Viktor GyökeresPenalty goals: 3 | Arsenal | 14 |
| 8 | Dominic Calvert-LewinPenalty goals: 4 | Leeds United | 14 |
| 9 | Danny WelbeckPenalty goals: 1 | Brighton and Hove Albion | 13 |
| 10 | Junior KroupiPenalty goals: 2 | Bournemouth | 13 |
| 11 | Jean-Philippe MatetaPenalty goals: 4 | Crystal Palace | 12 |
| 12 | Benjamin SeskoPenalty goals: 0 | Manchester United | 11 |
| 12 | Bryan MbeumoPenalty goals: 0 | Manchester United | 11 |
| 12 | Hugo EkitikéPenalty goals: 0 | Liverpool | 11 |
| 12 | RicharlisonPenalty goals: 0 | Tottenham Hotspur | 11 |
| 16 | Zian FlemmingPenalty goals: 2 | Burnley | 11 |
| 17 | Harry WilsonPenalty goals: 0 | Fulham | 10 |
| 17 | Matheus CunhaPenalty goals: 0 | Manchester United | 10 |
| 17 | Morgan RogersPenalty goals: 0 | Aston Villa | 10 |
| 20 | Enzo FernándezPenalty goals: 2 | Chelsea | 10 |
| 21 | Cole PalmerPenalty goals: 5 | Chelsea | 10 |
| 22 | BetoPenalty goals: 0 | Everton | 9 |
| 22 | CasemiroPenalty goals: 0 | Manchester United | 9 |
| 24 | Jarrod BowenPenalty goals: 1 | West Ham United | 9 |
| 25 | Bruno GuimarãesPenalty goals: 2 | Newcastle United | 9 |
| 26 | Ismaïla SarrPenalty goals: 3 | Crystal Palace | 9 |
| 27 | Bruno FernandesPenalty goals: 4 | Manchester United | 9 |
| 27 | Raul JiménezPenalty goals: 4 | Fulham | 9 |
| 29 | Jaidon AnthonyPenalty goals: 0 | Burnley | 8 |
| 29 | Kevin SchadePenalty goals: 0 | Brentford | 8 |
| 29 | Kiernan Dewsbury-HallPenalty goals: 0 | Everton | 8 |
| 29 | Noah OkaforPenalty goals: 0 | Leeds United | 8 |
| 29 | Thierno BarryPenalty goals: 0 | Everton | 8 |
| 34 | Nick WoltemadePenalty goals: 1 | Newcastle United | 8 |
| 35 | Brian BrobbeyPenalty goals: 0 | Sunderland | 7 |
| 35 | Callum WilsonPenalty goals: 0 | West Ham United | 7 |
| 35 | Cody GakpoPenalty goals: 0 | Liverpool | 7 |
| 35 | Dango OuattaraPenalty goals: 0 | Brentford | 7 |
| 35 | Eberechi EzePenalty goals: 0 | Arsenal | 7 |
| 35 | Harvey BarnesPenalty goals: 0 | Newcastle United | 7 |
| 35 | Phil FodenPenalty goals: 0 | Manchester City | 7 |
| 35 | William OsulaPenalty goals: 0 | Newcastle United | 7 |
| 43 | Bukayo SakaPenalty goals: 1 | Arsenal | 7 |
| 43 | Mohamed SalahPenalty goals: 1 | Liverpool | 7 |
| 45 | Marcus TavernierPenalty goals: 2 | Bournemouth | 7 |
| 46 | Dominik SzoboszlaiPenalty goals: 0 | Liverpool | 6 |
| 46 | Emiliano BuendíaPenalty goals: 0 | Aston Villa | 6 |
| 46 | EvanilsonPenalty goals: 0 | Bournemouth | 6 |
| 46 | Leandro TrossardPenalty goals: 0 | Arsenal | 6 |
| 46 | Valentín CastellanosPenalty goals: 0 | West Ham United | 6 |