| 1 | Robert LewandowskiPenalty goals: 5 | Bayern München | 34 |
| 2 | Timo WernerPenalty goals: 3 | RB Leipzig | 28 |
| 3 | Jadon SanchoPenalty goals: 0 | Borussia Dortmund | 17 |
| 4 | Wout WeghorstPenalty goals: 4 | VfL Wolfsburg | 16 |
| 5 | Rouwen HenningsPenalty goals: 4 | Fortuna Düsseldorf | 15 |
| 6 | Erling HaalandPenalty goals: 0 | Borussia Dortmund | 13 |
| 6 | Jhon CórdobaPenalty goals: 0 | 1. FC Köln | 13 |
| 8 | Florian NiederlechnerPenalty goals: 1 | FC Augsburg | 13 |
| 8 | Robin QuaisonPenalty goals: 1 | 1. FSV Mainz 05 | 13 |
| 10 | Serge GnabryPenalty goals: 0 | Bayern München | 12 |
| 11 | André SilvaPenalty goals: 1 | Eintracht Frankfurt | 12 |
| 11 | Kai HavertzPenalty goals: 1 | Bayer 04 Leverkusen | 12 |
| 11 | Sebastian AnderssonPenalty goals: 1 | 1. FC Union Berlin | 12 |
| 14 | Andrej KramaricPenalty goals: 2 | TSG 1899 Hoffenheim | 12 |
| 15 | Marco ReusPenalty goals: 1 | Borussia Dortmund | 11 |
| 15 | Nils PetersenPenalty goals: 1 | Sport-Club Freiburg | 11 |
| 17 | Alassane PléaPenalty goals: 0 | Borussia Mönchengladbach | 10 |
| 17 | Kevin VollandPenalty goals: 0 | Bayer 04 Leverkusen | 10 |
| 17 | Marcus ThuramPenalty goals: 0 | Borussia Mönchengladbach | 10 |
| 17 | Patrik SchickPenalty goals: 0 | RB Leipzig | 10 |
| 21 | Marcel SabitzerPenalty goals: 0 | RB Leipzig | 9 |
| 22 | Lars StindlPenalty goals: 2 | Borussia Mönchengladbach | 9 |
| 23 | Bas DostPenalty goals: 0 | Eintracht Frankfurt | 8 |
| 23 | Breel EmboloPenalty goals: 0 | Borussia Mönchengladbach | 8 |
| 23 | Lucas HölerPenalty goals: 0 | Sport-Club Freiburg | 8 |
| 23 | Martin HintereggerPenalty goals: 0 | Eintracht Frankfurt | 8 |
| 23 | Raphaël GuerreiroPenalty goals: 0 | Borussia Dortmund | 8 |
| 23 | Thomas MüllerPenalty goals: 0 | Bayern München | 8 |
| 23 | Yuya OsakoPenalty goals: 0 | SV Werder Bremen | 8 |
| 30 | Philipp MaxPenalty goals: 1 | FC Augsburg | 8 |
| 30 | Philippe CoutinhoPenalty goals: 1 | Bayern München | 8 |
| 32 | Milot RashicaPenalty goals: 2 | SV Werder Bremen | 8 |
| 33 | Christoph BaumgartnerPenalty goals: 0 | TSG 1899 Hoffenheim | 7 |
| 33 | Dodi LukébakioPenalty goals: 0 | Hertha BSC | 7 |
| 33 | Marius BülterPenalty goals: 0 | 1. FC Union Berlin | 7 |
| 33 | Suat SerdarPenalty goals: 0 | FC Schalke 04 | 7 |
| 33 | Thorgan HazardPenalty goals: 0 | Borussia Dortmund | 7 |
| 38 | Davy KlaassenPenalty goals: 1 | SV Werder Bremen | 7 |
| 38 | Gonçalo PaciênciaPenalty goals: 1 | Eintracht Frankfurt | 7 |
| 38 | Lucas AlarioPenalty goals: 1 | Bayer 04 Leverkusen | 7 |
| 38 | Vedad IbisevicPenalty goals: 1 | Hertha BSC | 7 |
| 42 | Gian-Luca WaldschmidtPenalty goals: 3 | Sport-Club Freiburg | 7 |
| 43 | Erik ThommyPenalty goals: 0 | Fortuna Düsseldorf | 6 |
| 43 | Ihlas BebouPenalty goals: 0 | TSG 1899 Hoffenheim | 6 |
| 43 | Kenan KaramanPenalty goals: 0 | Fortuna Düsseldorf | 6 |
| 43 | Leon GoretzkaPenalty goals: 0 | Bayern München | 6 |
| 43 | Patrick HerrmannPenalty goals: 0 | Borussia Mönchengladbach | 6 |
| 43 | Renato SteffenPenalty goals: 0 | VfL Wolfsburg | 6 |
| 43 | Rubén VargasPenalty goals: 0 | FC Augsburg | 6 |
| 43 | Sebastiaan BornauwPenalty goals: 0 | 1. FC Köln | 6 |