| 1 |  Robert LewandowskiPenalty goals: 0 |  Barcelona | 23 |
| 2 |  Karim BenzemaPenalty goals: 7 |  Real Madrid | 19 |
| 3 |  JoseluPenalty goals: 5 |  Espanyol | 16 |
| 4 |  Antoine GriezmannPenalty goals: 0 |  Atlético de Madrid | 15 |
| 5 |  Vedat MuriqiPenalty goals: 4 |  Mallorca | 15 |
| 6 |  Borja IglesiasPenalty goals: 5 |  Real Betis | 15 |
| 7 |  Enes ÜnalPenalty goals: 5 |  Getafe | 14 |
| 8 |  Álvaro MorataPenalty goals: 0 | Atlético de Madrid | 13 |
| 9 |  Valentín CastellanosPenalty goals: 1 |  Girona | 13 |
| 10 |  Alexander SørlothPenalty goals: 0 |  Real Sociedad | 12 |
| 10 |  Nicolas JacksonPenalty goals: 0 |  Villarreal | 12 |
| 12 |  Iago AspasPenalty goals: 2 |  Celta de Vigo | 12 |
| 13 |  Gabriel VeigaPenalty goals: 0 | Celta de Vigo | 11 |
| 14 |  Martin BraithwaitePenalty goals: 0 | Espanyol | 10 |
| 14 |  Vinícius JúniorPenalty goals: 0 | Real Madrid | 10 |
| 16 |  Iñaki WilliamsPenalty goals: 1 |  Athletic Club | 10 |
| 17 |  Oihan SancetPenalty goals: 2 | Athletic Club | 10 |
| 18 |  Ángel CorreaPenalty goals: 0 | Atlético de Madrid | 9 |
| 18 |  Marco AsensioPenalty goals: 0 | Real Madrid | 9 |
| 18 |  Takefusa KuboPenalty goals: 0 | Real Sociedad | 9 |
| 21 |  Isi PalazónPenalty goals: 1 |  Rayo Vallecano | 9 |
| 21 |  RodrygoPenalty goals: 1 | Real Madrid | 9 |
| 23 |  Cristhian StuaniPenalty goals: 5 | Girona | 9 |
| 24 |  Ante BudimirPenalty goals: 0 |  Osasuna | 8 |
| 24 |  Borja MayoralPenalty goals: 0 | Getafe | 8 |
| 24 |  Brais MéndezPenalty goals: 0 | Real Sociedad | 8 |
| 24 |  Youssef En-NesyriPenalty goals: 0 |  Sevilla | 8 |
| 28 |  Cyle LarinPenalty goals: 2 |  Real Valladolid | 8 |
| 28 |  Ezequiel ÁvilaPenalty goals: 2 | Osasuna | 8 |
| 30 |  Ansu FatiPenalty goals: 0 | Barcelona | 7 |
| 30 |  El Bilal TouréPenalty goals: 0 |  Almería | 7 |
| 30 |  Federico ValverdePenalty goals: 0 | Real Madrid | 7 |
| 30 |  Javi PuadoPenalty goals: 0 | Espanyol | 7 |
| 30 |  José Luis MoralesPenalty goals: 0 | Villarreal | 7 |
| 30 |  Lucas BoyéPenalty goals: 0 |  Elche | 7 |
| 30 |  RaphinhaPenalty goals: 0 | Barcelona | 7 |
| 37 |  Gerard MorenoPenalty goals: 1 | Villarreal | 7 |
| 37 |  Yannick CarrascoPenalty goals: 1 | Atlético de Madrid | 7 |
| 39 |  Álex BaenaPenalty goals: 0 | Villarreal | 6 |
| 39 |  Érik LamelaPenalty goals: 0 | Sevilla | 6 |
| 39 |  Gorka GuruzetaPenalty goals: 0 | Athletic Club | 6 |
| 39 |  Kang-In LeePenalty goals: 0 | Mallorca | 6 |
| 39 |  LázaroPenalty goals: 0 | Almería | 6 |
| 39 |  Nico WilliamsPenalty goals: 0 | Athletic Club | 6 |
| 39 |  PedriPenalty goals: 0 | Barcelona | 6 |
| 39 |  Rafa MirPenalty goals: 0 | Sevilla | 6 |
| 39 |  Samuel ChukwuezePenalty goals: 0 | Villarreal | 6 |
| 39 |  Samuel Dias LinoPenalty goals: 0 |  Valencia CF | 6 |
| 39 |  Sergi DarderPenalty goals: 0 | Espanyol | 6 |
| 39 |  Sergio CamelloPenalty goals: 0 | Rayo Vallecano | 6 |
